Ramoplanin (A-16686), a new glycolipodepsipeptide antibiotic. IV. Complete sequence determination by homonuclear 2D NMR spectroscopy.

نویسندگان

  • J K Kettenring
  • R Ciabatti
  • G Winters
  • G Tamborini
  • B Cavalleri
چکیده

Homonuclear 2D NMR spectroscopy double quantum filter correlation spectroscopy (DQF-COSY), relayed-COSY, nuclear Overhauser enhancement spectroscopy (NOESY), and DQF-relayed-NOESY) allowed the complete determination of the core depsipeptide of antibiotic ramoplanin (A-16686). In particular, the DQF-relayed-NOESY experiments were essential in assigning the single signals close to the diagonal.

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عنوان ژورنال:
  • The Journal of antibiotics

دوره 42 2  شماره 

صفحات  -

تاریخ انتشار 1989